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SiAlBaCa Alloy

SiAlBaCa Alloy

Silicon aluminum barium calcium (sialbaca) alloy is a multi-element alloy containing silicon, aluminum, barium and calcium. It is an efficient deoxidizer and desulfurizer in barium alloys. It is usually in block or granular form, with a silver-gray metallic luster on the surface. The general composition ratio is Si>30%, Ca>6%, Ba>9%, and Al>8%.
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Shape: Lump Powder Particles
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Chemical Composition:Si Ca Ba Al Mn P S
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Size:0~1mm  1~3mm 10mm~50mm 10~60mm 10~100mm .etc
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Package: Ton bag or customized according to customer requirements
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Product Introduction

Silicon aluminum barium calcium (sialbaca) alloy is a composite alloy composed of multiple elements including silicon (Si), aluminum (Al), barium (Ba), and calcium (Ca). It is a high-performance deoxidizer and desulfurizer among barium-based alloys. This product has a silvery-gray metallic luster and is typically supplied in block, granular, or powder form. As a key auxiliary material in modern steel smelting and casting industries, SiAlBaCa Alloy, through the synergistic effect of its multiple elements, can significantly improve the purity of molten steel and enhance the mechanical properties of castings, making it an ideal upgrade from traditional single deoxidizers.

 

Production process

1

Ore method: First, silica, bauxite and coke are mixed evenly, added to the smelting furnace to produce silicon aluminum alloy. Then CaO and coke are added in batches to promote the formation of silicon calcium aluminum. Barium ore and coke are added in batches to promote the formation of silicon aluminum barium calcium alloy.

 
2

Hot-punching aluminum ingot method: When producing silicon calcium barium in a large electric furnace, the method of hot-punching aluminum ingots is used to produce silicon aluminum barium calcium alloy, but this method is not as economically efficient as the ore method.

 

SiAlBaCa Alloy   SiAlBaCa Alloy

chemical composition

Brand Si (%) Ca (%) Ba (%) Al (%) Mn (%) ≤ C (%) ≤ P (%) ≤ S (%) ≤
Al16Ba9Ca12Si30 ≥30 ≥12 ≥9 ≥16 0.4 0.5 0.04 0.05
Al12Ba9Ca2Si35 ≥35 ≥9 ≥9 ≥12 0.4 0.5 0.04 0.05
Al18Ba12Ca6Si40 ≥40 ≥6 ≥12 ≥8 0.4 0.5 0.04 0.05
Al18Ba15Ca6Si40 ≥40 ≥6 ≥15 ≥8 0.4 0.5 0.04 0.05
Al16Ba18Ca6Si40 ≥40 ≥6 ≥18 ≥6 0.4 0.5 0.04 0.05

 

Note: Data in the table are typical values; specific compositions can be customized according to customer requirements.

 

Physical Form and Packaging
Size:
0-3mm, 3-8mm, 8-15mm, 10-60mm, 10-100mm, or customized according to customer requirements

Product Form: Blocks, Granules, Powder

Packaging: 1-ton bags, or steel drums, or customized according to customer requirements.

Mechanism of Action

 

1. Deoxidation Mechanism

Silicon, aluminum, and calcium are all strong deoxidizing elements. They can react with dissolved oxygen in molten steel to generate stable oxides, thereby significantly reducing the total oxygen content in the molten steel:

 Silicon (Si): A basic deoxidizing element, generating SiO₂

 Aluminum (Al): A strong deoxidizer, generating Al₂O₃, with high deoxidation efficiency

 Calcium (Ca): A strong deoxidizing element, generating CaO

 Barium (Ba): Although its own deoxidizing ability is relatively weak, it can significantly reduce the vapor pressure of calcium, increase the solubility and utilization rate of calcium in molten steel, and indirectly enhance the deoxidation effect.

Studies have shown that when using barium-containing alloys (such as SiAlBaCa) as deoxidizers, the total oxygen content in molten steel can be reduced to extremely low levels, and deoxidation products are easily floated and removed.

 

2. Desulfurization Mechanism

Calcium has a very strong affinity for sulfur and can react with sulfur in molten steel to generate CaS, thereby effectively removing sulfur. The presence of aluminum further enhances the desulfurization effect, forming an aluminum-calcium dual composite desulfurization mechanism.

 

3. Inclusion Modification Mechanism

Traditional deoxidation produces Al₂O₃ inclusions that are brittle and irregular in shape, affecting the fatigue performance and machinability of steel. After deoxidation of silicon-aluminum-barium-calcium alloys, complex oxides containing calcium, barium, silicon, and aluminum are formed. These inclusions have the following advantages:

 Low density: Easily floats and is removed from molten steel.

 Improved morphology: Transforms into spherical, uniformly distributed fine inclusions.

 Increased toughness: Significantly improves the impact toughness and machinability of the steel.

 

SiAlBaCa SiAlBaCa

Main uses

 

1. Iron and Steel Smelting Industry

Silicon aluminum barium calcium alloy is a highly efficient auxiliary material in the steelmaking process, suitable for deoxidation in various steelmaking methods, especially for converter steelmaking.

 

Application Scenarios:

Steel Types Specific Applications Main Benefits
Low Carbon Steel and Cold Heading Steel Automotive fasteners, standard parts steel Reduced oxygen content, improving cold heading performance and preventing cracking
Pipeline Steel API 5L X70/X80 oil and gas pipelines Sulfur content controlled at ≤0.005%, preventing welding hot cracking
High Strength Low Alloy Steel (HSLA) Automotive structural components, construction machinery Oxygen content reduced to ≤20ppm, improving strength and toughness
Stainless Steel 300 series, 400 series stainless steel Purifying molten steel and improving corrosion resistance
Continuously Cast Steel Slab and billet continuous casting Completely solving the problem of nozzle clogging and preventing steel spillage accidents

 

Core Advantages:

 Strong Deoxidation and Desulfurization: Simultaneously achieves deep deoxidation and efficient desulfurization.
 Improved Steel Fluidity: Significantly improves steel fluidity and resolves nozzle clogging.
 Reduced Gas and Inclusions: Reduces the gas content (H₂, N₂) in steel, minimizing inclusions.
 Increased Recovery Rate: High element recovery rate; non-combustible, non-explosive, and non-splashing.

 

2. Cast Iron Production

In cast iron production, silicon aluminum barium calcium alloy is not only a highly efficient inoculant but also possesses excellent deoxidation and desulfurization effects.

 

Application Scenarios:

Gray Cast Iron: Promotes graphitization, improves graphite morphology and distribution, and enhances the mechanical properties of castings.

Ductile Cast Iron: Refines graphite nodules, increases spheroidization rate, and enhances casting toughness.

Vermicular Graphite Cast Iron: Stable acquisition of vermicular graphite, optimizing overall performance.

Core Advantages:

Significant Inoculation Effect: Effectively promotes graphitization and refines eutectic clusters.

Reduced White Casting Tendency: Reduces white cast iron content in castings and improves machinability.

Enhanced Mechanical Properties: Improves tensile strength, hardness, and wear resistance.

 

3. Composite Alloy Comparison and Selection Guide

To help customers select the most suitable product based on their specific needs, the following is a performance comparison of sialbaca alloy with other silicon-based multi-element alloys:

 

Performance Indicators SiBa SiBaCa SiAlBaCa
Deoxidation Capacity Medium (Si+Ba synergistic) Strong (Ca-enhanced deoxidation) Excellent (Al+Si+Ba+Ca multi-stage deoxidation)
Desulfurization Efficiency Low-Medium High (Ca forms CaS) Very high (Al+Ca dual composite desulfurization)
Inclusion Modification Basic (Spherical Oxide) Good (brittle inclusions → ductility) Excellent (fine, dispersed distribution)
Grain Refinement Mild Medium Strong (Al promotes fine grain strengthening)
Applicable Steel Grades Common Carbon Steel, Cast Steel Low sulfur steel, pipeline steel HSLA steel, stainless steel, special alloys
Cost Level Low Medium Moderately high (due to aluminum content)

 

Silicon aluminum barium calcium alloys  Silicon aluminum barium calcium alloys

FAQ

 

Q: What are the advantages of sialbaca alloys compared to traditional calcium silicon alloys?

A: Silicon aluminum barium calcium alloys add aluminum and barium to the silicon calcium alloy base. Aluminum further enhances the deoxidation effect, while barium improves the utilization rate of calcium. Simultaneously, it forms composite inclusions that are easier to float, resulting in better purification and reduced steelmaking costs.

 

Q: Can you provide customized compositions?

A: Yes. We can adjust the proportions of each element in the alloy according to the customer's specific steel grade requirements and process conditions to achieve optimal deoxidation, desulfurization, and inclusion modification effects.

 

Q: What are the minimum order quantity and sample policy?

A: The minimum order quantity for regular products is 20-25 tons. We also accept small batch orders for customer testing and can provide free samples.

 

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